For the air conditioning and refrigeration (ACR) industry, C12200 (DHP copper) is the engineering standard, primarily because it is deoxidized with phosphorus to prevent hydrogen embrittlement. While C11000 (ETP copper) offers a superior thermal conductivity of 388 W/m·K, its internal oxygen content (0.02 to 0.04 percent) makes it susceptible to catastrophic cracking during the high-temperature brazing required for refrigerant lines. If your assembly involves torch brazing or TIG welding, switching to a phosphorus-deoxidized grade is a safety mandate. You can evaluate our available industrial tubing and flat products on the C11000 sheet.
Does the 0.04% oxygen in C11000 really cause leaks in refrigerant lines?
Yes. The trace amount of oxygen in electrolytic tough pitch copper exists as cuprous oxide particles. During brazing, hydrogen from the torch flame diffuses into the copper and reacts with these oxides to form water vapor (steam) inside the metal grain boundaries. This internal pressure creates microscopic voids that lead to "slow leaks" or total joint failure under the high pressure of modern refrigerants.
As detailed in our technical analysis of whether C11000 copper is oxygen free, this specific chemical reaction is the primary reason why C11000 is restricted to bolted electrical connections rather than brazed plumbing. For engineers sourcing material in Asia, the JIS C1100 grade faces the same limitation-it is a high-performance conductor but a high-risk welding material.
Critical Material Data for HVAC Designers
| Technical Metric | C11000 (Cu-ETP) | C12200 (Cu-DHP) | Engineering Impact |
| Phosphorus Content | None / Trace | 0.015 to 0.040 percent | Deoxidation / Weldability |
| Thermal Conductivity | 388 W/m·K | 339 W/m·K | Heat exchange efficiency |
| Electrical Conductivity | 101 percent IACS min | 85 percent IACS approx | Energy loss at terminals |
| Hydrogen Resistance | Poor (High Risk) | Excellent (Immune) | Joining reliability |
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When should you prioritize C11000 thermal speed over C12200 safety?
If your cooling system uses mechanical expansion (where the tube is physically "pressed" into the fin) or ultrasonic welding instead of brazing, c11000 material is technically superior. Its thermal conductivity is approximately 15 percent higher than C12200, allowing for more efficient heat transfer in high-density electronics cooling.
For B2B buyers focused on copper vs aluminum heatsinks, using a high-purity C11000 base plate often provides the necessary thermal "headroom" that aluminum cannot reach. However, if that base plate must be brazed to a cooling manifold, you must reconsider the difference between C11000 and C12200 to avoid internal porosity.
Fabrication Compatibility Checklist
Mechanical Bolt/Clamp: C11000 (Best Economy / Max Conductivity)
Ultrasonic Welding: C11000 (Standard for battery packs)
Soft Soldering (<350C): C11000 (Safe / High Performance)
Torch Brazing/Welding: C12200 (Mandatory for safety)
High-Vacuum Seal: C11000 vs C10100 (OFC is required)
Consult a Material Expert for a Joining Audit
How does phosphorus affect the long-term corrosion of copper tubes?
In many water-handling and industrial environments, the deoxidized structure of C12200 provides slightly better resistance to "pitting" corrosion compared to t2 copper. The phosphorus helps stabilize the protective oxide film that forms on the inner wall of the tube. For procurement managers, this means a longer service life in HVAC condensers and evaporators, where moisture and chemicals are constantly present.
If your project involves the fabrication of C11000 vs C12200 tubes for a liquid cooling loop, the reliability of the joint often outweighs the slight loss in thermal speed. For stationary parts like a C11000 electrical copper busbar, the oxygen-bearing ETP grade remains the more logical and cost-effective choice.
Comparative Joint Integrity and Pressure Rating
| Factor | C11000 (ETP Copper) | C12200 (DHP Copper) |
| Brazed Joint Strength | Unreliable (Brittle) | Excellent (Ductile) |
| Corrosion in Water | Moderate | Superior Resistance |
| Ductility (Bending) | [C110 copper is bendable -> #14] | Excellent (Soft Annealed) |
| Gas Tightness | Risk of Porosity | Guaranteed leak-proof |
FAQ: Sourcing Copper for HVAC and Refrigeration
1. Is C11000 considered "pure copper"?
Yes. Both C11000 and C12200 are commercially pure coppers with 99.90 percent min purity. The difference is the "deoxidizer" used during refining, not the overall copper content.
2. Can I use a special flux to braze C11000 safely?
Flux only protects the surface of the metal. It cannot prevent the hydrogen from diffusing into the c11000 copper and reacting with the internal oxygen. For brazing, a grade change is safer than a flux change.
3. Why is C11000 cheaper than C12200?
C11000 is produced in massive global volumes for the electrical industry, making the fabrication premium much lower. C12200 is a specialized industrial grade for the HVAC market.
4. How do I confirm if my copper is oxygen-free or deoxidized?
Check the Mill Test Certificate (MTC). If the phosphorus (P) content is between 0.015 and 0.040 percent, it is C12200. If the oxygen (O) is below 10 ppm, it is an oxygen-free grade, as discussed in our is C110 copper oxygen free report.
5. Which grade is better for high-frequency induction heating?
For induction coils, C12200 or oxygen-free coppers are preferred because the coils are almost always brazed to water-cooling fittings. C11000 welding and brazing guides highlight the risks of using ETP in these high-heat assemblies.
6. Do you provide custom-bent cooling tubes?
Yes. We provide both the raw material and the finished fabrication. We can supply CNC-bent tubes in both C11000 and C12200 with custom flared ends or brazed fittings.
Product Specifications & Range
| Product Category | Common Grades (Alloys) | Size Range (Dimensions) | Standards |
| Copper Rods | C11000, C12200, C10200, C14500 | Diameter: 3mm – 400mm<br>Shape: Round, Hexagonal, Square | ASTM B187, EN 12163 |
| Copper Tubes | C11000, C12200 (DHP), C10200 (OF), C27200 | OD: 2mm – 219mm<br>Wall Thickness: 0.2mm – 20mm | ASTM B280, EN 12735 |
| Copper Plates | C11000 (ETP), C10200, C12200 | Thickness: 0.1mm – 150mm<br>Width: Up to 2500mm | ASTM B152, DIN 1751 |
| Copper Wires | C11000, C10200, Brass Wire | Diameter: 0.05mm – 10.0mm<br>Form: Spool or Coil | ASTM B3, EN 13602 |
| Copper Strips | C11000, C12200, C26800 (Brass) | Thickness: 0.05mm – 3.0mm<br>Width: 5mm – 610mm | ASTM B19, EN 1652 |
Customization Note:
Custom Dimensions: We provide precision cutting and slitting services to meet your specific project requirements.
Tempers Available: Soft (O), Half-Hard (H02), Full Hard (H04), and Spring Hard (H08).
Surface Finish: Bright annealing, Polished, or Plated (Tin, Silver, Nickel) upon request.
Industrial-Grade Export Packaging
Maximum protection against oxidation, moisture, and transit damage.
1. Anti-Oxidation Protection
VCI Paper & Moisture-Proof Film: Every order is vacuum-sealed or wrapped in anti-corrosion materials to ensure the copper remains bright and tarnish-free during sea freight.
2. Reinforced Structural Support
Seaworthy Wooden Crates: We use reinforced, fumigation-free wooden cases (ISPM-15) and steel strapping for rods, tubes, and heavy plates to prevent bending or surface scratches.
3. Secure Handling & Loading
Forklift-Ready Pallets: All materials are secured on standardized export pallets for easy unloading and maximum stability in containers.
4. Clear Identification
Professional Labeling: Each package includes detailed labels with heat numbers, specifications, and net weight for efficient inventory management.





Advanced Manufacturing & Quality Control
1. Core Production Equipment
Up-casting & Continuous Casting Lines: Ensures high-purity oxygen-free copper rods and wires with uniform grain structure.
High-Precision Cold/Hot Rolling Mills: Automated thickness control for copper plates and strips with tolerances within ±0.01mm.
Large-Scale Extrusion & Drawing Machines: Capable of producing seamless copper tubes and rods in diverse diameters and shapes.
Atmospheric Controlled Annealing Furnaces: Bright annealing process to achieve specific tempers (Soft, Half-hard, Hard) without surface oxidation.
2. In-House Testing Center
Direct-Reading Spectrometers: Instant chemical composition analysis to guarantee Cu purity and precise alloying (Brass, Bronze, etc.).
Universal Tensile Testers: Verifying mechanical properties including tensile strength, elongation, and yield strength.
Eddy Current & Ultrasonic Testing: 100% non-destructive inspection for tubes and rods to detect internal cracks or flaws.
Conductivity & Hardness Testers: Ensuring electrical conductivity (IACS) and Vickers/Rockwell hardness meet international standards (ASTM, EN, DIN).





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