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UNS-C44300-Admiralty-Brass-Tube.pdf

C44300 Copper Tubing: Composition and Uses

Introduction

This article explains what C44300 copper tubing is, covering composition and uses. Admiralty brass, designated C44300, is a copper-zinc-tin alloy developed for seawater and brackish-water heat exchange service. Small additions of tin and arsenic suppress dezincification, which is the common failure mode of plain brasses in chloride-bearing water.

Composition

Admiralty brass contains 70.0 to 73.0 percent copper, 0.9 to 1.2 percent tin and 0.02 to 0.10 percent arsenic with the balance zinc. The tin strengthens the alloy and moves the corrosion mechanism away from selective leaching, while the arsenic addition further blocks the dezincification reaction at the grain boundaries. Common international equivalents include CuZn28Sn1 under EN standards and CZ111 under British designations.

Why It Resists Seawater

In plain brass, chloride water attacks the zinc-rich phase and leaves a porous copper deposit, a process called dezincification. The tin and arsenic in admiralty brass inhibit that reaction, which is why the alloy passes dezincification testing per ASTM B858 and gives decades of service in condensers cooled with clean or moderately polluted seawater.

Element Typical Range
Copper 70.0 - 73.0%
Tin 0.9 - 1.2%
Arsenic 0.02 - 0.10%
Zinc Balance

Properties

Admiralty brass tube combines a thermal conductivity of about 109 to 111 W/(m·K) with tensile strength of roughly 330 to 380 MPa annealed and elongation above 40 percent. Density is about 8.53 g/cm3. The alloy resists corrosion by seawater, brine and non-oxidizing acids, and it has practical immunity to stress-corrosion cracking in the annealed condition.

Applications and Standards

The main use is condenser and heat exchanger tubing in power plants, desalination plants, ships and refinery coolers. Tube is supplied to ASTM B111, with size and temper tolerances per the same standard, and the material is also available as sheet, strip, rod and pipe.

Verification

Confirm the copper, tin and arsenic ranges on the mill certificate, check the dezincification test requirement, and verify the tube dimensions and temper against ASTM B111 before acceptance.

FAQ

1. What is admiralty brass? A 70/30 copper-zinc alloy with tin and arsenic additions, designated C44300, for seawater heat exchange service.
2. Why are tin and arsenic added? They suppress dezincification, the selective removal of zinc that destroys plain brass in salt water.
3. What is the composition? 70.0 to 73.0 percent copper, 0.9 to 1.2 percent tin, 0.02 to 0.10 percent arsenic, balance zinc.
4. Where is it used? Condenser and heat exchanger tubes in power, desalination, marine and refinery applications.
5. What are the equivalents? CuZn28Sn1 under EN standards and CZ111 under British designations.
6. Which standard covers the tube? ASTM B111 for seamless condenser and heat exchanger tube.

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