ASTM B111 is the governing standard for seamless copper alloy heat exchanger and condenser tubes. For C68700 specifically, the standard defines chemical composition, mechanical properties, dimensional tolerances, testing requirements, and marking. Understanding these requirements helps buyers verify that delivered tubes meet specification.
Many tube failures trace back to material that never actually met ASTM B111 requirements. Either the chemistry was wrong, the temper was incorrect, or the tubes were never properly tested. This article explains what the standard requires and how to verify compliance.
What Chemical Composition Does ASTM B111 Require for C68700?
The standard specifies exact percentages for each alloying element. These percentages are not optional or "typical" - they are requirements.
Required chemical composition (weight %):
| Element | Minimum (%) | Maximum (%) | Typical (%) |
|---|---|---|---|
| Copper (Cu) | 76.0 | 79.0 | 77.5 |
| Aluminum (Al) | 1.8 | 2.5 | 2.0 |
| Arsenic (As) | 0.02 | 0.06 | 0.03 |
| Zinc (Zn) | Remainder | Remainder | ~20.5 |
| Lead (Pb) | - | 0.03 | <0.01 |
| Iron (Fe) | - | 0.06 | <0.03 |
| Other elements (total) | - | 0.3 | - |
Critical notes on chemistry:
Both aluminum AND arsenic must be present. Missing either means the tube does not meet C68700 specifications.
Zinc is the remainder after all other elements are accounted for.
Lead and iron are impurities and should be low.
Verification method: Request the mill test report (MTR) and confirm each element falls within the required range. A third-party lab can perform independent analysis if questions arise.

What Mechanical Properties Are Required?
ASTM B111 specifies minimum tensile strength, yield strength, and elongation for C68700 tubes. These properties vary slightly by temper.
Mechanical requirements for C68700 (O61 annealed temper):
| Property | ASTM B111 Requirement | Typical Value |
|---|---|---|
| Tensile strength (min) | 50,000 psi (345 MPa) | 55,000-65,000 psi |
| Yield strength (min, 0.5% extension) | 18,000 psi (124 MPa) | 20,000-25,000 psi |
| Elongation (min, 2" gauge length) | 30% | 35-45% |
For H55 (light drawn) temper:
Tensile strength: higher than O61 (typically 55,000-65,000 psi min)
Elongation: lower than O61 (typically 15-25%)
Verification method: MTR must report actual tensile test results from the mill. The values must meet or exceed the minimum requirements. Values below the minimum indicate non-compliant material.
What Dimensional Tolerances Does ASTM B111 Specify?
Tube dimensions must fall within specified tolerances. These tolerances are important for proper tube-to-tubesheet fit.
Outside diameter tolerance:
| Tube OD (mm) | Tolerance (± mm) |
|---|---|
| Up to 25.4 mm (1") | 0.05 mm |
| 25.4 mm to 50.8 mm (1-2") | 0.08 mm |
| Over 50.8 mm (2") | 0.10 mm |
Wall thickness tolerance:
| Wall Thickness (mm) | Tolerance (± mm) |
|---|---|
| Up to 1.65 mm | 0.08 mm |
| 1.65 mm to 3.05 mm | 0.10 mm |
| Over 3.05 mm | 0.13 mm |
Length tolerance:
Tubes up to 6 meters (20 feet): +6 mm / -0 mm
Tubes over 6 meters: +10 mm / -0 mm
Important note: The standard allows tubes to be longer than specified but not shorter. This ensures tubes will reach across the tubesheet.
Verification method: Random sample measurement using calibrated micrometers and tape measure. Sample size should be at least 5-10 tubes per bundle or per heat lot.
What Tests Are Required by ASTM B111?
The standard mandates specific tests that must be performed on each heat lot.
Required tests:
| Test | Purpose | Acceptance Criteria |
|---|---|---|
| Chemical analysis | Verify alloy composition | Elements within specified ranges |
| Tensile test | Verify strength and ductility | Meets minimum values |
| Flattening test | Check ductility and seam quality | No cracks after flattening |
| Expansion test | Check ductility (for tubes under 50mm OD) | No cracks after expansion |
| Hydrostatic or eddy current test | Detect leaks and defects | No leakage (hydro) or no signals exceeding reference (ECT) |
Eddy current testing (ECT) note: ASTM B111 permits either hydrostatic testing or eddy current testing. Most modern mills use ECT because it is faster and detects smaller defects. The ECT reference standard is typically a tube with 1.6mm diameter through-hole (for tubes under 25.4mm OD).
Verification method: MTR must include results of all required tests. For eddy current testing, the MTR should state that tubes were tested and met reference standard requirements.
What Temper Conditions Are Recognized by ASTM B111?
The standard recognizes multiple tempers for C68700, but O61 (annealed) is the most common for heat exchanger tubes.
Common tempers for C68700:
| Temper | Condition | Typical Use |
|---|---|---|
| O61 | Soft, annealed | Roller expansion into tubesheets |
| H55 | Light drawn | Retubing, tighter clearance |
| H80 | Hard drawn | Special applications (rare) |
How temper affects tube properties:
O61: Lowest strength, highest ductility, easiest to expand
H55: Higher strength, lower ductility, harder to expand
H80: Highest strength, lowest ductility, difficult to expand
Verification method: Temper is typically verified by hardness testing. O61 should measure 60-80 HRF; H55 measures 70-90 HRF. MTR should report temper and, ideally, hardness values.
How Must Tubes Be Marked per ASTM B111?
The standard specifies marking requirements for traceability and identification.
Required marking information:
Manufacturer name or trademark
ASTM designation (B111)
Alloy designation (C68700)
Temper (O61, H55, etc.)
Size (OD and wall thickness, or BWG gauge)
Marking format example:
"SMITH TUBE ASTM B111 C68700 O61 19.05mm x 1.245mm"
Marking requirements:
Must be legible and permanent
Must appear at least once every 3 meters (10 feet)
Can be printed, stenciled, or stamped (but stamping should not damage tube)
Verification method: Visual inspection of received tubes. Tubes without proper markings should be rejected as non-compliant.
FAQ
1. What is the difference between ASTM B111 and ASME SB111?
ASTM B111 and ASME SB111 are technically identical. ASME SB111 is the ASME Boiler and Pressure Vessel Code adoption of ASTM B111. Tubes meeting ASTM B111 automatically meet ASME SB111 requirements. The only practical difference is that ASME SB111 may require additional documentation for Code-stamped vessels. If a heat exchanger requires an ASME U-stamp, specify "ASME SB111 C68700." For non-Code applications, ASTM B111 is sufficient.
2. Does ASTM B111 require seamless construction for C68700 tubes?
Yes. ASTM B111 specifically requires seamless tubes for heat exchanger and condenser service. Welded tubes are not permitted under this standard. Seamless tubes provide uniform wall thickness and no weld seam corrosion risk. Any supplier offering welded tubes as "ASTM B111 compliant" is incorrect. Welded tubes may meet other standards (e.g., ASTM B359 for finned tubes) but not B111 for smooth-bore heat exchanger tubes.
3. What is the difference between "minimum wall" and "nominal wall" in ASTM B111?
ASTM B111 specifies tolerances around a nominal wall thickness. For example, a tube ordered as 1.245mm nominal wall (18 BWG) can be as thin as 1.165mm (1.245mm - 0.08mm tolerance). "Minimum wall" tubes are manufactured to the low end of the tolerance range - they are technically compliant but have less corrosion allowance. Some suppliers quote "minimum wall" to appear cheaper. Buyers should specify whether they require nominal wall or minimum wall.
4. How many samples must be tested per heat lot?
ASTM B111 does not specify a fixed sample size. Instead, it requires testing that is representative of the heat lot. Industry practice: two tensile specimens per heat lot (one from each end of the lot) and chemical analysis from one sample per heat. For eddy current testing, every tube is tested (100%) because ECT is non-destructive and fast. Buyers can request additional testing or larger sample sizes in their purchase order.
5. What does "O61" mean in ASTM B111?
O61 is the temper designation for annealed tubes. The "O" indicates annealed (soft). The "61" is a code indicating the specific annealing process and resulting properties. For C68700, O61 is the standard temper for heat exchanger tubes because it provides maximum ductility for roller expansion. Other tempers (H55, H80) are available but are less common. The MTR should clearly state the temper designation.
6. Can ASTM B111 C68700 tubes be supplied in non-standard lengths?
Yes. ASTM B111 allows tubes to be cut to any specified length. Length tolerance remains +6mm / -0mm for tubes up to 6m, +10mm / -0mm for longer tubes. Custom lengths are common and do not require deviation from the standard. Buyers should specify exact length requirements in the purchase order. There is no minimum length specified in ASTM B111, though practical manufacturing limits apply for very short tubes.
7. What is the hydrostatic test pressure required by ASTM B111?
ASTM B111 does not specify a fixed hydrostatic test pressure. Instead, it requires a pressure sufficient to detect leaks, typically based on tube dimensions. Common practice: test pressure of 1,000-3,000 psi for most heat exchanger tube sizes. Alternatively, eddy current testing may be substituted for hydrostatic testing. The MTR should indicate which test was performed and the results (leak-free for hydro, or reference standard for ECT).
8. How are C68700 tubes identified if the markings wear off?
Tube markings are required to be permanent but can wear off during handling or installation. For this reason, each bundle should also have a tag with heat number and specifications. The heat number links tubes back to the MTR. If markings wear off, tubes can still be identified by bundle and position. For critical traceability, some buyers mark tubes with additional permanent identification or maintain a map of which tube came from which heat lot.
9. Does ASTM B111 allow tube ends to be deburred?
Yes, but deburring is not explicitly required. The standard requires tubes to be free of burrs that would interfere with installation. Most buyers specify deburred ends in their purchase order. Deburring removes sharp edges that can damage tube sheet gaskets or injure installers. Suppliers typically deburr as a standard practice, but buyers should confirm. There is no additional cost for deburring on most orders.
10. What is the straightness tolerance for C68700 tubes per ASTM B111?
ASTM B111 does not specify a numerical straightness tolerance. Instead, it requires tubes to be "reasonably straight" and free from kinks. Industry interpretation: maximum bow of 1.5mm per meter (0.060" per foot) is generally acceptable. For critical applications, buyers should specify a straightness tolerance in the purchase order. Mills can hold tighter tolerances (e.g., 0.75mm/m) for an additional cost.
11. Can ASTM B111 C68700 tubes be supplied with protective coatings?
Yes, but coatings are not addressed in the standard. Protective coatings (e.g., epoxy, phenolic) are available for additional corrosion protection. However, coatings add cost and may affect heat transfer. For most seawater condensers, coatings are unnecessary because C68700 relies on its natural oxide film. Coated tubes are more common in specialized applications (e.g., fouling service). Buyers should request coating specifications separately from the ASTM B111 standard.
Inspection Capabilities
Each batch of ASTM B111 C68700 tubes undergoes a complete inspection process before shipment. Inspection items include: chemical analysis (verifying copper content of 76.0-79.0%, aluminum of 1.8-2.5%, and arsenic of 0.02-0.06% per specification), mechanical property testing (tensile strength ≥50,000 psi, yield strength ≥18,000 psi, elongation ≥30%), eddy current testing (100% inspection using a 1.6mm through-hole reference standard), flattening testing, and expansion testing. All test results are recorded on the Mill Test Report (MTR) provided with each shipment, and every tube is traceable to its specific heat lot. For orders with special requirements, third-party inspection (such as SGS or BV) can be arranged at the buyer's request.


Export-Ready Packing – Anti-Rust & Wooden Case
After passing inspection, all tubes are packed according to export standards and customer-specific requirements. The packing process is documented below to ensure traceability and damage-free delivery.
Packing steps shown in video & images:
1. Tube cleaning & drying
2. Plastic end caps on both ends
3. VCI anti-rust paper wrapping
4. Bundle strapping with moisture barrier film
5. Plywood wooden case (ISPM-15 compliant) with foam padding
6. Labeling with ASTM grade, lot number, and inspection stamp



Our Factory & Equipment
All ASTM C68700 tubes are produced and inspected on our in-house equipment, allowing full process control from billet casting to final packing.
Key equipment used for this lot:
• Induction melting furnace – precise alloying (Cu + Zn + Al + As)
• Horizontal continuous casting – uniform billet structure
• Extrusion press (800T / 1630T) – seamless tube forming
• Cold drawing bench (5–40m) – dimensional accuracy to ±0.02mm
• Online eddy current tester (FOERSTER / MAC) – 100% NDT
• Ultrasonic wall thickness gauge – real-time monitoring
• Annealing furnace (controlled atmosphere) – temper O61
In-house metrology: Micrometers, pin gauges, optical comparator, hardness tester (HV/HRB)
All equipment is calibrated quarterly. Production records are traceable by lot number.



Copper & Copper Alloy Products – Supply Range
| Product Form | Common Alloys / Grades | Size Range | Standards | Typical Applications |
|---|---|---|---|---|
| Tube / Pipe | C12200, C11000, C68700, C70600, C71500, C44300, C27000 | OD: 4mm – 219mm Wall: 0.5mm – 20mm Length: up to 15m |
ASTM B68, B75, B111, B280, B359, B466 | Heat exchangers, condensers, HVAC, plumbing, oil coolers |
| Plate / Sheet | C11000, C12200, C26000, C26800, C52100, C68700 | Thk: 0.5mm – 50mm Width: up to 1200mm Length: up to 4000mm |
ASTM B152, B169, B103, B465 | Electrical parts, roofing, gaskets, industrial panels |
| Rod / Bar | C11000, C26000, C36000, C46400, C48500, C63000 | Dia: 3mm – 120mm Length: 1m – 6m (or custom) |
ASTM B16, B124, B138, B150, B453 | Valve stems, shafts, fasteners, machined components |
| Wire | C11000, C16200, C17500, C26000, C52100, C64700 | Dia: 0.1mm – 12mm Coil weight: up to 100kg |
ASTM B1, B2, B3, B197, B206, B624 | Welding electrodes, electrical conductors, springs, mesh |
| Strip / Foil | C11000, C19400, C26000, C26800, C52100, C70250 | Thk: 0.05mm – 3.0mm Width: 5mm – 600mm |
ASTM B36, B465, B694, B888 | Connectors, terminals, battery tabs, shielding, stamping parts |
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